Zinc oxide (cas 1314-13-2)
Product Identification
Product Name: Zinc oxide
Synonyms: zinc oxide heavy; c.i. pigment white 4; flowers of zinc; zinc white; zinc oxide,edible; active zinc oxide; zinkoxyd aktiv; zinci oxidum; activox; activox b; actox14; zine oxide; zine white; zincoxide; actox16; actox216; ai3-00277; akro-zincbar85; akro-zincbar90; amalox; azo22; azo-33; azo-55; azo-55tt; azo-66; azo-66tt
CAS:1314-13-2
Formula:OZn
Molecular Weight:81.37
EINECS:215-222-5
RTECS:ZH4810000
RTECS Class:Mutagen; Reproductive Effector; Human Data; Primary Irritant
Merck:12,10279
Beilstein/Gmelin:17338 (G)
EC Index Number:030-013-00-7
EC Class:dangerous for the environment
InChI:InChI=1/O.Zn/rOZn/c1-2
First Aid Measures
Ingestion:Never give anything by mouth to an
unconscious person. Get medical aid. Do NOT induce vomiting. If
conscious and alert, rinse mouth and drink 2-4 cupfuls of milk or water.
Inhalation:Remove
from exposure to fresh air immediately. If not breathing, give
artificial respiration. If breathing is difficult, give oxygen. Get
medical aid. DO NOT use mouth-to-mouth respiration. If breathing has
ceased apply artificial respiration using oxygen and a suitable
mechanical device such as a bag and a mask.
Skin:Get
medical aid. Flush skin with plenty of soap and water for at least 15
minutes while removing contaminated clothing and shoes. Wash clothing
before reuse.
Eyes:Immediately flush eyes with
plenty of water for at least 15 minutes, occasionally lifting the upper
and lower eyelids. Get medical aid.
Handling and Storage
Storage:Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances.
Handling:Minimize
dust generation and accumulation. Avoid breathing dust, vapor, mist, or
gas. Avoid contact with eyes, skin, and clothing. Keep container
tightly closed. Avoid ingestion and inhalation. Use with adequate
ventilation. Wash clothing before reuse.
Exposure Controls/Personal Protection
Personal Protection:Eyes: Wear appropriate
protective eyeglasses or chemical safety goggles as described by OSHA's
eye and face protection regulations in 29 CFR 1910.133 or European
Standard EN166. Skin: Wear appropriate protective gloves to prevent skin
exposure. Clothing: Wear appropriate protective clothing to prevent
skin exposure.
Respirators:A respiratory protection
program that meets OSHA's 29 CFR 1910.134 and ANSI Z88.2 requirements or
European Standard EN 149 must be followed whenever workplace conditions
warrant a respirator's use.
Exposure Effects:Effects may be delayed.
Exposure limit(s):NIOSH REL: Dust: TWA 5 mg/m3 C 15 mg/m3 Fume: TWA 5 mg/m3 ST 10 mg/m3 NIOSH IDLH: 500 mg/m3
Poison Class:-
Physical and Chemical Properties
Appearance:White or yellowish-white powder or crystals, odorless.
Solubility in water:4 mg/L (25 C)
Melting Point:1975
Boiling Point:2360
Density:5.6 g/cm3
Usage:Accelerator
activator, pigment and reinforcing agent in rubber, ointments, pigment
and mould-growth inhibitor in paints, uv absorber in plastics, ceramics,
floor tile, glass, zinc salts, feed additive, dietary supplement, seed
treatment cosmetics, photoconductor in office copying machines and in
colour photography, piezoelectric devices, artists' colorant.
Refractive Index:2.0041 (20 C)
Hazards Identification
Inhalation:Effects may be delayed. Causes
respiratory tract irritation. Inhalation of fumes may cause metal fume
fever, which is characterized by flu-like symptoms with metallic taste,
fever, chills, cough, weakness, chest pain, muscle pain and increased
white blood cell count. Can produce delayed pulmonary edema. Zinc oxide
dust is considered to be of low toxicity and is classified as a nuisance
particulate by the ACGIH. However, inhalation fumes or very fine dust
may causes zinc fume fever, which is characterized by flu-like symptoms
with metallic taste, coughing, weakness, fatigue, m uscular pain, and
nausea, followed by fever and chills. Onset of sympt oms occurs about
4-12 hours after exposure.
Skin:Causes skin irritation. Prolonged and/or repeated contact may cause irritation and/or dermatitis.
Eyes:Dust may cause mechanical irritation. Causes eye irritation. May cause chemical conjunctivitis.
Ingestion:May cause gastrointestinal irritation with nausea, vomiting and diarrhea. Moderately toxic to humans by ingestion.
Hazards:May
ignite on contact with water or moist air. Some react vigorously or
explosively on contact with water. May be ignited by heat, sparks or
flames. May re-ignite after fire is extinguished. May be transported in
highly flammable liquids.
EC Risk Phrase:R 50/53
EC Safety Phrase:S 60 61
UN (DOT):1435
Transport Information
UN Number:1435
Packing Group:III
HS Code:2817 00 00
Fire Fighting Measures
Flash Point:1436
Fire Fighting:Wear
a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH
(approved or equivalent), and full protective gear. Material will not
burn. During a fire, irritating and highly toxic gases may be generated
by thermal decomposition or combustion. Wear appropriate protective
clothing to prevent contact with skin and eyes. Wear a self-contained
breathing apparatus (SCBA) to prevent contact with thermal decomposition
products. Extinguishing media: Substance is noncombustible; use agent
most appropriate to extinguish surrounding fire. In case of fire use
water spray, dry chemical, carbon dioxide, or appropriate foam.
Fire Potential:Produce flammable gases on contact with water.
Accidental Release Measures
Small spills/leaks:Vacuum or sweep up material and
place into a suitable disposal container. Clean up spills immediately,
using the appropriate protective equipment. Avoid generating dusty
conditions. Provide ventilation.
Stability and Reactivity
Incompatibilities:Magnesium, chlorinated rubber, strong oxidizing agents.
Stability:Stable at room temperature in closed containers under normal storage and handling conditions.
Decomposition:Toxic fumes of zinc oxide.
Combustion Products:Fire will produce irritating, corrosive and/or toxic gases.